Advances in Bioengineering by Pier Andrea Serra

By Pier Andrea Serra

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Precursor type effect The precursor type is one of the most important factors in plasma treatments. For instance, in plasma polymerization, the use of a non-saturated monomer like allylamine is advantageous compared to saturated ones because in the former case less energy is needed for the polymer‐ ization process. In fact, the double bond in allylamine encourages a deposition by a combina‐ tion of plasma and conventional free-radical polymerization. Because of that, allylamine typically polymerizes at low energies.

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Effect on film’s atomic composition: Martin et al. [68] also studied the effect of power on the atomic composition of the layers using XPS analysis. High power yielded relatively lower surface concentration of nitrogen atoms than the use of low power: by varying the power from 80 W to 10 W nitrogen content increased by ca. 15%. This is due to the more successful breakdown of the monomer molecule achieved at higher power, yielding layers which present less nitrogen atoms. This behavior has also been observed by Shard et al.

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